Photochlorination is a chlorination reaction that is initiated by light. Usually a C-H bond is converted to a C-Cl bond. Photochlorination is carried out on an industrial scale. The process is exothermic and proceeds as a chain reaction initiated by the homolytic cleavage of molecular chlorine into chlorine radicals by … See more Chlorination is one of the oldest known substitution reactions in chemistry. The French chemist Jean-Baptiste Dumas investigated the substitution of hydrogen for chlorine by acetic acid in candle wax as early as 1830. He … See more Chloromethanes An example of photochlorination at low temperatures and under ambient pressure is the chlorination of chloromethane to dichloromethane. … See more • H. Hartig: Einfache Dimensionierung, photochemischer Reaktoren. In: Chemie Ingenieur Technik – CIT. 42, 1970, p. 1241–1245, See more Photochlorinations are usually effected in the liquid phase, usually employing chemically inert solvents. Alkane substrates The photochlorination of hydrocarbon is unselective, although the reactivity of the C-H bonds is … See more Sulfochlorination The sulfochlorination first described by Cortes F. Reed in 1936 proceeds under almost identical conditions as the conventional … See more WebReferences(20) As a new photochemical process for synthesizing 1,1-dichloroethylene (VC) from 1,1-dichloroethane (1,1-DCE), the laser-induced photochlorination of 1,1-DCE followed by its dehydrochlor
(PDF) Photochlorination Reactor - ResearchGate
WebSiCl_4中SiHCl_3的去除及检测方法研究进展.pdf WebReactors up to 50 m³ are realized with this proven design and a safe scale-up by our specialists enables further reactor sizes. The UV Light Sources - Safe Operation. The light … simpson rough cut hangers
Photochlorination of toluene – the thin line between …
WebThis work aims to intensify the photochlorination of toluene, see Fig. 1. Therefore, the impact of various reactor concepts and operation conditions on the reaction rate as well … WebA method of describing the behavior of a single-phase, photochemical reaction in a tubular flow reactor is given. A simplified form of the equations is applied to experimental data … WebPhotochemical reactions, such as the light-driven side-chain chlorination of various aromatic compounds, are among the cornerstones of the chemical industry. Therefore, reoptimising reaction conditions using state-of-the-art reactor designs and irradiation techniques is economically and ecologically of uttermost importance. razir transport winnipeg